ODB connectors are held in place with two plastic tabs on the port itself, on both sides of the connector. Either push it in (you can reach it by releasing the driver's under panels) or pull it in by grabbing the connector itself, until you hear them click. it's possible that your odb connector is not making a solid connection.
As for scanning the car, I have never scanned the car for errors since I learned that almost any cars I scan, it will come up with some errors which is not relevant to what's wrong with the car. most of those errors are some options not installed on my car to some changes I have made to my car. That brake system error looks scary so check it out.
Here are the listings of all the codes for alfa romeo Alfa Romeo Diagnostic Trouble Code (DTC) Definition, Causes and Diagnosis
As for scanning the car, I have never scanned the car for errors since I learned that almost any cars I scan, it will come up with some errors which is not relevant to what's wrong with the car. most of those errors are some options not installed on my car to some changes I have made to my car. That brake system error looks scary so check it out.
Here are the listings of all the codes for alfa romeo Alfa Romeo Diagnostic Trouble Code (DTC) Definition, Causes and Diagnosis